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I would like to change the details of the PayPal account from which you take my subscription payment. How can I do this.

You will need to cancel your existing subscription from the Admin > Cancel Subscription. It will open the PayPal page and you will need to login with your current PayPal email to do that.

Then you can subscribe from Admin > Start Subscription to start your new subscription.

wait, does this mean when I downgrade my Payap Pro account toa standard account I have to cancel my subscription to E-Junkie first? I was told I could make such a downgrade of payapl without impacting my account or pay-now buttons.

The PayPal email you use to pay your subscription doesn't necessarily bear any relation to the PayPal email where you receive buyer payments. They can happen to be the same, but they don't have to be.

If you will be keeping the same PayPal email for your PayPal account when downgrading it from Pro to standard, you should not need to change your PayPal email with E-junkie in any regard; just make sure your Seller Admin > Edit Payment Preferences gets set to "Show PayPal Standard" instead of "PayPal Website Payments Pro".